Alonso struck in the ninth minute when his 20-yard shot deflected off Jose Bosingwa and left Petr Cech wrong-footed.
It was Chelsea's first defeat under new boss Luiz Felipe Scolari, but Liverpool were always in charge of a pulsating contest at Stamford Bridge and look real title contenders on this form.
Chelsea had not been beaten at home since Arsenal's 2-1 success in February 2004 but Liverpool deserved their triumph with an impressive display.
Liverpool went ahead in the ninth minute with their first attack of the game.
Chelsea failed to deal with a thrown-in when John Terry could only half-clear Dirk Kuyt's clever back-header.
The ball fell to Alonso on the edge of the penalty area and his shot deflected off Chelsea right-back Bosingwa into the net.



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